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@ARTICLE{Gl:860040,
      author       = {Glöβ, Maria and Pütt, Ricarda and Moors, Marco and
                      Kentzinger, Emmanuel and Pyckhout-Hintzen, Wim and Monakhov,
                      Kirill},
      title        = {{I}nterplay between the amphipathic polyoxometalate
                      interactions in solution and at solid–liquid interfaces: a
                      toolbox for the technical application},
      journal      = {Nanoscale},
      volume       = {11},
      number       = {10},
      issn         = {2040-3372},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2019-00837},
      pages        = {4267-4277},
      year         = {2019},
      abstract     = {The far-reaching interplay between the speciation of
                      polyoxometalates (POMs) in the liquid phase and the POM
                      adsorption characteristics on substrate surfaces yet remains
                      to be understood. The significance of this interplay is
                      however paramount because it indicates the degree of
                      technical applicability of solvent-processable POM
                      molecules. Herein, we target this fundamentally important
                      issue, shedding light on the
                      “POM–counterion–solvent” and
                      “POM–counterion–solvent–substrate” processes. We
                      effectively combine the results from small-angle X-ray
                      scattering in solution with surface sensitive scanning
                      tunneling microscopy and X-ray photoelectron spectroscopy
                      measurements and present on this basis a semi-quantitative
                      analysis which provides an excellent correlation between
                      both approaches. The MeCN-solution speciation of a
                      tris(alkoxo)-ligated Wells–Dawson-type polyoxoanion –
                      explored as a representative of commonly negatively charged
                      POM-based inorganic–organic nanostructures – is
                      strikingly connected with the growth of porous
                      two-dimensional molecular layers on highly oriented
                      pyrolytic graphite (HOPG). Low water amounts dramatically
                      transform intermolecular relationships toward hierarchical
                      agglomeration that inhibits the layer formation on HOPG. The
                      obtained findings lay the groundwork for a mechanistic study
                      of controlled nucleation and growth of POM nanostructures on
                      weakly interacting surfaces},
      cin          = {PGI-7 / JARA-FIT / JCNS-2 / Neutronenstreuung ; JCNS-1 /
                      PGI-4},
      ddc          = {600},
      cid          = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$ /
                      I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)JCNS-1-20110106 /
                      I:(DE-Juel1)PGI-4-20110106},
      pnm          = {524 - Controlling Collective States (POF3-524) / 144 -
                      Controlling Collective States (POF3-144) / 6212 - Quantum
                      Condensed Matter: Magnetism, Superconductivity (POF3-621) /
                      6213 - Materials and Processes for Energy and Transport
                      Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
                      Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-524 / G:(DE-HGF)POF3-144 /
                      G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6213 /
                      G:(DE-HGF)POF3-6G4},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30566161},
      UT           = {WOS:000465410200051},
      doi          = {10.1039/C8NR08008A},
      url          = {https://juser.fz-juelich.de/record/860040},
}