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100 1 _ |a Lobe, Sandra
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245 _ _ |a Challenges regarding thin film deposition of garnet electrolytes for all-solid-state lithium batteries with high energy density
260 _ _ |a Heidelberg
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520 _ _ |a In this work, we studied the deposition of garnet electrolyte thin films in order to realize an all-solid-state battery with high energy density. Therefore, in a first step we investigated the stability of the garnet Li5La3Ta2O12 with the spinel LiCoMnO4 in order to determine the temperature window for a successful thin film deposition on high-voltage spinels. A mixture of both materials showed a thermal stability up to 600 °C, so that all-solid-state batteries could be realized when the electrolyte is applied at a low deposition temperature. The second part of the work was the thin film deposition of Li5La3Ta2O12 by a sputter deposition process. When a stoichiometric Li5La3Ta2O12 sputter target was used, the surface of the target showed a depletion of lithium after several depositions, which leads to decreasing Li content in the thin films. In order to compensate the lithium loss we enriched the target with LiOH∙H
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536 _ _ |a BMBF-03SF0477A - DESIREE : Defektspinelle als Hochenergie- und Hochleistungsmaterialien zur elektrochemischen Energiespeicherung, Teilprojekte: Partikelmikrostrukturierung und Modellsysteme, Makroskopische und atomistische Analyse von elektrochemischen Vorgängen (BMBF-03SF0477A)
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773 _ _ |a 10.1007/s11581-018-2594-3
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