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@ARTICLE{Zhang:860226,
author = {Zhang, Qiubo and Shi, Zhe and Yin, Kuibo and Dong, Hui and
Xu, Feng and Peng, Xinxing and Yu, Kaihao and Zhang, Hongtao
and Chen, Chia-Chin and Valov, Ilia and Zheng, Haimei and
Sun, Litao},
title = {{S}pring-{L}ike {P}seudoelectroelasticity of
{M}onocrystalline {C}u 2 {S} {N}anowire},
journal = {Nano letters},
volume = {18},
number = {8},
issn = {1530-6992},
address = {Washington, DC},
publisher = {ACS Publ.},
reportid = {FZJ-2019-01010},
pages = {5070 - 5077},
year = {2018},
abstract = {Prediction from the dual-phase nature of superionic
conductors—both solid and liquid-like—is that mobile
ions in the material may experience reversible
extraction–reinsertion by an external electric field.
However, this type of pseudoelectroelasticity has not been
confirmed in situ, and no details on the microscopic
mechanism are known. Here, we in situ monitor the
pseudoelectroelasticity of monocrystalline Cu2S nanowires
(NWs) using transmission electron microscopy (TEM).
Specifically, we reveal the atomic scale details including
phase transformation, migration and redox reactions of Cu+
ions, nucleation, growth, as well as spontaneous shrinking
of Cu protrusion. Caterpillar-diffusion-dominated
deformation is confirmed by the high-resolution transmission
electron microscopy (HRTEM) observation and ab initio
calculation, which can be driven by either an external
electric field or chemical potential difference. The
observed spring-like behavior was creatively adopted for
electric nanoactuators. Our findings are crucial to
elucidate the mechanism of pseudoelectroelasticity and could
potentially stimulate in-depth research into electrochemical
and nanoelectromechanical systems.},
cin = {PGI-7 / JARA-FIT},
ddc = {660},
cid = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:29965777},
UT = {WOS:000441478300061},
doi = {10.1021/acs.nanolett.8b01914},
url = {https://juser.fz-juelich.de/record/860226},
}