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@ARTICLE{Liu:860249,
author = {Liu, Yulong and Sun, Qian and Zhao, Yang and Wang, Biqiong
and Kaghazchi, Payam and Adair, Keegan R. and Li, Ruying and
Zhang, Cheng and Liu, Jingru and Kuo, Liang-Yin and Hu,
Yongfeng and Sham, Tsun-Kong and Zhang, Li and Yang, Rong
and Lu, Shigang and Song, Xiping and Sun, Xueliang},
title = {{S}tabilizing the {I}nterface of {NASICON} {S}olid
{E}lectrolyte against {L}i {M}etal with {A}tomic {L}ayer
{D}eposition},
journal = {ACS applied materials $\&$ interfaces},
volume = {10},
number = {37},
issn = {1944-8252},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2019-01033},
pages = {31240 - 31248},
year = {2018},
abstract = {Solid-state batteries have been considered as one of the
most promising next-generation energy storage systems
because of their high safety and energy density. Solid-state
electrolytes are the key component of the solid-state
battery, which exhibit high ionic conductivity, good
chemical stability, and wide electrochemical windows. LATP
[Li1.3Al0.3Ti1.7 (PO4)3] solid electrolyte has been widely
investigated for its high ionic conductivity. Nevertheless,
the chemical instability of LATP against Li metal has
hindered its application in solid-state batteries. Here, we
propose that atomic layer deposition (ALD) coating on LATP
surfaces is able to stabilize the LATP/Li interface by
reducing the side reactions. In comparison with bare LATP,
the Al2O3-coated LATP by ALD exhibits a stable cycling
behavior with smaller voltage hysteresis for 600 h, as well
as small resistance. More importantly, on the basis of
advanced characterizations such as high-resolution
transmission electron spectroscope-electron energy loss
spectroscopy, the lithium penetration into the LATP bulk and
Ti4+ reduction are significantly limited. The results
suggest that ALD is very effective in improving solid-state
electrolyte/electrode interface stability.},
cin = {IEK-1},
ddc = {600},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30141900},
UT = {WOS:000445439900034},
doi = {10.1021/acsami.8b06366},
url = {https://juser.fz-juelich.de/record/860249},
}