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024 7 _ |a 10.1016/j.jmst.2016.09.027
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100 1 _ |a Lu, Jiangbo
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245 _ _ |a Microstructure and secondary phases in epitaxial LaBaCo 2 O 5.5+δ thin films
260 _ _ |a Shenyang
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|b Ed. Board, Journal of Materials Science & Technology
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520 _ _ |a Aberration-corrected scanning transmission electron microscopy was employed to investigate the microstructures and secondary phases in LaBaCo2O5.5 + δ (LBCO) thin films grown on SrTiO3 (STO) substrates. The as-grown films showed an epitaxial growth on the substrates with atomically sharp interfaces and orientation relationships of [100]LBCO//[100]STO and (001)LBCO//(001)STO. Secondary phases were observed in the films, which strongly depended on the sample fabrication conditions. In the film prepared at a temperature of 900 °C, nano-scale CoO pillars nucleated on the substrate, and grew along the [001] direction of the film. In the film grown at a temperature of 1000 °C, isolated nano-scale Co3O4 particles appeared, which promoted the growth of {111} twinning structures in the film. The orientation relationships and the interfaces between the secondary phases and the films were illustrated, and the growth mechanism of the film was discussed.
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700 1 _ |a Lu, Lu
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700 1 _ |a Cheng, Sheng
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700 1 _ |a Liu, Ming
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700 1 _ |a Jia, Chunlin@fz-juelich. de
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773 _ _ |a 10.1016/j.jmst.2016.09.027
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