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@ARTICLE{Haque:860635,
      author       = {Haque, Md Azimul and Gandi, Appala Naidu and Mohanraman,
                      Rajeshkumar and Weng, Yakui and Davaasuren, Bambar and
                      Emwas, Abdul‐Hamid and Combe, Craig and Baran, Derya and
                      Rothenberger, Alexander and Schwingenschlögl, Udo and
                      Alshareef, Husam N. and Dong, Shuai and Wu, Tom},
      title        = {{A} 0{D} {L}ead‐{F}ree {H}ybrid {C}rystal with {U}ltralow
                      {T}hermal {C}onductivity},
      journal      = {Advanced functional materials},
      volume       = {29},
      number       = {13},
      issn         = {1616-3028},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2019-01308},
      pages        = {1809166},
      year         = {2019},
      abstract     = {Organic–inorganic hybrid materials are of significant
                      interest owing to their diverse applications ranging from
                      photovoltaics and electronics to catalysis. Control over the
                      organic and inorganic components offers flexibility through
                      tuning their chemical and physical properties. Herein, it is
                      reported that a new organic–inorganic hybrid,
                      [Mn(C2H6OS)6]I4, with linear tetraiodide anions exhibit an
                      ultralow thermal conductivity of 0.15 ± 0.01 W m−1 K−1
                      at room temperature, which is among the lowest values
                      reported for organic–inorganic hybrid materials.
                      Interestingly, the hybrid compound has a unique 0D
                      structure, which extends into 3D supramolecular frameworks
                      through nonclassical hydrogen bonding. Phonon band structure
                      calculations reveal that low group velocities and
                      localization of vibrational energy underlie the observed
                      ultralow thermal conductivity, which could serve as a
                      general principle to design novel thermal management
                      materials.},
      cin          = {IEK-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000463732400025},
      doi          = {10.1002/adfm.201809166},
      url          = {https://juser.fz-juelich.de/record/860635},
}