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@ARTICLE{Lenser:860737,
author = {Lenser, Christian and Menzler, Norbert H.},
title = {{I}mpedance characterization of supported oxygen ion
conducting electrolytes},
journal = {Solid state ionics},
volume = {334},
issn = {0167-2738},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2019-01401},
pages = {70 - 81},
year = {2019},
abstract = {Electrochemical impedance spectroscopy is a widely used
tool to study electrochemical reactions in batteries, fuel
cells and other electrochemical energy conversion devices.
However, conduction processes in the electrolyte of high
temperature fuel or electrolysis cells (SOFC / SOEC) are
inacessible during operation, severely restricting the
information that can be obtained about performance and
degradation of the electrolyte. Using the distribution
function of relaxation times (DRT), we study the ionic
conduction properties and degradation phenomena in
multi-layered solid electrolytes, ex situ and at low
temperatures. The investigation of full cells in air enables
a detailed analysis of the conductivity of supported
electrolytes as thin as 1 μm, as well as the relative
contributions of multilayered electrolytes. Furthermore,
three case studies are presented concerning the degradation
mechanism in SOFC and SOEC operation, showcasing the ability
of this technique to distinguish the effects of grain
boundary contamination, formation of solid solutions and the
formation of porosity on the ionic conductivity of thin,
supported electrolytes.Keywords: SOFC; SOEC; Impedance
spectroscopy; DRT; electrolyte;},
cin = {IEK-1},
ddc = {530},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000463981900011},
doi = {10.1016/j.ssi.2019.01.031},
url = {https://juser.fz-juelich.de/record/860737},
}