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@ARTICLE{Mousavi:860769,
author = {Mousavi, Mahdiyeh and Gompper, Gerhard and Winkler, Roland
G.},
title = {{A}ctive {B}rownian ring polymers},
journal = {The journal of chemical physics},
volume = {150},
number = {6},
issn = {1089-7690},
address = {Melville, NY},
publisher = {American Institute of Physics},
reportid = {FZJ-2019-01432},
pages = {064913},
year = {2019},
abstract = {The conformational and dynamical properties of semiflexible
active Brownian ring polymers are investigated analytically.
A ring is described by the Gaussian semiflexible polymer
model accounting for the finite contour length. Activity is
implemented by a Gaussian, non-Markovian stochastic process
resembling either an external nonthermal force or a local
self-propulsion velocity as for an active Ornstein-Uhlenbeck
particle. Specifically, the fluctuation spectrum of
normal-mode amplitudes is analyzed. At elevated activities,
flexible (tension) modes dominate over bending modes even
for semiflexible rings, corresponding to enhanced
conformational fluctuations. The fluctuation spectrum
exhibits a crossover from a quadratic to a quartic
dependence on the mode number with increasing mode number,
originating from intramolecular tension, but the relaxation
behavior is either dominated by intra-polymer processes or
the active stochastic process. A further increase in
activity enhances fluctuations at large length scales at the
expense of reduced fluctuations at small scales.
Conformationally, the mean square ring diameter exhibits
swelling qualitatively comparable to liner polymers. The
ring’s diffusive dynamics is enhanced, and the mean square
displacement shows distinct activity-determined regimes,
consecutively, a ballistic, a subdiffusive, and a diffusive
regime. The subdiffusive regime disappears gradually with
increasing activity},
cin = {IAS-2},
ddc = {530},
cid = {I:(DE-Juel1)IAS-2-20090406},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551)},
pid = {G:(DE-HGF)POF3-551},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30769972},
UT = {WOS:000458879800056},
doi = {10.1063/1.5082723},
url = {https://juser.fz-juelich.de/record/860769},
}