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@ARTICLE{Shamblin:860940,
author = {Shamblin, Jacob and Tracy, Cameron L. and Palomares, Raul
I. and O'Quinn, Eric C. and Ewing, Rodney C. and Neuefeind,
Joerg and Feygenson, Mikhail and Behrens, Jason and
Trautmann, Christina and Lang, Maik},
title = {{S}imilar local order in disordered fluorite and aperiodic
pyrochlore structures},
journal = {Acta materialia},
volume = {144},
issn = {1359-6454},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science85412},
reportid = {FZJ-2019-01583},
pages = {60 - 67},
year = {2018},
abstract = {A major challenge to understanding the response of
materials to extreme environments (e.g., nuclear fuels/waste
forms and fusion materials) is to unravel the processes by
which a material can incorporate atomic-scale disorder, and
at the same time, remain crystalline. While it has long been
known that all condensed matter, even liquids and glasses,
possess short-range order, the relation between
fully-ordered, disordered, and aperiodic structures over
multiple length scales is not well understood. For example,
when defects are introduced (via pressure or irradiation)
into materials adopting the pyrochlore structure, these
complex oxides either disorder over specific
crystallographic sites, remaining crystalline, or become
aperiodic. Here we present neutron total scattering results
characterizing the irradiation response of two pyrochlores,
one that is known to disorder (Er2Sn2O7) and the other to
amorphize (Dy2Sn2O7) under ion irradiation. The results
demonstrate that in both cases, the local pyrochlore
structure is transformed into similar short range
configurations that are best fit by the orthorhombic
weberite structure, even though the two compositions have
distinctly different structures, aperiodic vs.
disordered-crystalline, at longer length scales. Thus, a
material's resistance to amorphization may not depend
primarily on local defect formation energies, but rather on
the structure's compatibility with meso-scale modulations of
the local order in a way that maintains long-range
periodicity.},
cin = {ICS-1 / Neutronenstreuung ; JCNS-1},
ddc = {670},
cid = {I:(DE-Juel1)ICS-1-20110106 / I:(DE-Juel1)JCNS-1-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000424067100007},
doi = {10.1016/j.actamat.2017.10.044},
url = {https://juser.fz-juelich.de/record/860940},
}