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000861055 1001_ $$0P:(DE-Juel1)129669$$aVan Gestel, Tim$$b0$$eCorresponding author
000861055 245__ $$aNew types of graphene-based membranes with molecular sieve properties for He, H2 and H2O
000861055 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2018
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000861055 520__ $$aGraphene oxide (GO) and graphene membranes were fabricated by dip-coating a GO dispersion on a specially designed 8YSZ mesoporous membrane. With the use of a reductive thermal treatment at 750 °C, it was possible to obtain a graphene membrane with permselectivities of 215, 80 and 170, for the gas pairs He/N2, H2/CO2 and H2/N2, respectively, and the H2 permeance reached ∼ 7·10−8 mol m−2 s−1 Pa−1. High H2O permeance and selectivity was achieved by processing a GO membrane in air at 300 °C. In pervaporation with H2O/IPA mixtures (5% H2O), the resulting membrane selectively separated H2O (separation factor > 800) and a flux of 4–8 kg m−2 h−1 was achieved at 70 °C.
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000861055 7001_ $$0P:(DE-Juel1)130525$$aBarthel, Juri$$b1
000861055 773__ $$0PERI:(DE-600)1491419-0$$a10.1016/j.memsci.2018.02.034$$gVol. 554, p. 378 - 384$$p378 - 384$$tJournal of membrane science$$v554$$x0376-7388$$y2018
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