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001     861055
005     20210130000709.0
024 7 _ |a 10.1016/j.memsci.2018.02.034
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024 7 _ |a 0376-7388
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024 7 _ |a 1873-3123
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037 _ _ |a FZJ-2019-01639
082 _ _ |a 570
100 1 _ |a Van Gestel, Tim
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245 _ _ |a New types of graphene-based membranes with molecular sieve properties for He, H2 and H2O
260 _ _ |a New York, NY [u.a.]
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520 _ _ |a Graphene oxide (GO) and graphene membranes were fabricated by dip-coating a GO dispersion on a specially designed 8YSZ mesoporous membrane. With the use of a reductive thermal treatment at 750 °C, it was possible to obtain a graphene membrane with permselectivities of 215, 80 and 170, for the gas pairs He/N2, H2/CO2 and H2/N2, respectively, and the H2 permeance reached ∼ 7·10−8 mol m−2 s−1 Pa−1. High H2O permeance and selectivity was achieved by processing a GO membrane in air at 300 °C. In pervaporation with H2O/IPA mixtures (5% H2O), the resulting membrane selectively separated H2O (separation factor > 800) and a flux of 4–8 kg m−2 h−1 was achieved at 70 °C.
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700 1 _ |a Barthel, Juri
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773 _ _ |a 10.1016/j.memsci.2018.02.034
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