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@ARTICLE{Koll:861060,
author = {Koll, Rieke and Fruhner, Lisa Sarah and Heller, Hauke and
Allgaier, Jürgen and Pyckhout-Hintzen, Wim and Kruteva,
Margarita and Feoktystov, Artem and Biehl, Ralf and
Förster, Stephan and Weller, Horst},
title = {{C}reating a synthetic platform for the encapsulation of
nanocrystals with covalently bound polymer shells},
journal = {Nanoscale},
volume = {11},
number = {9},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2019-01644},
pages = {3847-3854},
year = {2019},
abstract = {We present a platform for the encapsulation of
superparamagnetic iron oxide nanocrystals (SPIONs) with a
highly stable diblock copolymer shell allowing a homogeneous
dispersion of the nanocrystals into a polymer matrix in the
resulting nanocomposites. High polymer shell stability was
achieved by crosslinking the inner polydiene shell for
example in a persulfate based redox process. The advantage
of this crosslinking reaction is the avoidance of heat and
UV light for the initiation, making it suitable for heat or
UV sensitive systems. In addition, we were able to minimize
the ligand excess needed for the encapsulation and showcased
a variation of molecular weight and composition as well as
different ligands which lead to stable micelles. The
encapsulated nanocrystals as well as the nanocomposite
materials were characterized by transmission electron
microscopy (TEM) and small angle scattering (SAXS and
SANS).},
cin = {JCNS-1 / ICS-1 / JCNS-FRM-II},
ddc = {600},
cid = {I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6215},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30758011},
UT = {WOS:000465409000006},
doi = {10.1039/C8NR10018G},
url = {https://juser.fz-juelich.de/record/861060},
}