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000861135 245__ $$aExperimental Thermodynamic Investigation of the Liquid Cu-Li-Sn System by Knudsen Effusion Mass Spectrometry 2
000861135 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2019
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000861135 520__ $$aThe thermodynamic activity of lithium was measured by Knudsen Effusion Mass Spectrometry (KEMS) within the Cu-Li-Sn system in the liquid region. For this purpose, eleven samples were studied between 773 and 1078 K in the Sn-rich part of the Cu-Li-Sn phase diagram. Mixing enthalpies, entropies and Gibbs energies were derived directly from the measured thermodynamic activity. The measured thermodynamic activities of Li were fitted to the Redlich-Kister-Muggianu (RKM) sub-regular solution model, by taking ternary interactions into account, using a mathematical regression procedure. Thereby, the partial and integral excess thermodynamic properties, the activities of Li, Cu and Sn and the ternary interaction L-parameters, as a function of temperature, were obtained.
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000861135 7001_ $$0P:(DE-Juel1)129722$$aHenriques, D.$$b1
000861135 7001_ $$0P:(DE-Juel1)129761$$aMotalov, V.$$b2$$eCorresponding author
000861135 7001_ $$0P:(DE-HGF)0$$aKovács, Á. Kolay$$b3
000861135 7001_ $$0P:(DE-Juel1)129756$$aMarkus, T.$$b4
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