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@ARTICLE{Frielinghaus:861201,
      author       = {Frielinghaus, Henrich and Koch, Kerstin and Antonio,
                      Viviane Pecanha and Noda, Yohei and Koizumi, Satoshi},
      title        = {{T}he locally columnar model for clay/polymer systems:
                      {C}onnections to scattering experiments},
      journal      = {Journal of colloid and interface science},
      volume       = {544},
      issn         = {0021-9797},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2019-01733},
      pages        = {172 - 177},
      year         = {2019},
      abstract     = {A tight connection of scattering to thermodynamic models is
                      missing for clay systems. A new approach called “locally
                      columnar model” gives an attempt for making this
                      connection. The scattering model assumes an up-lining of
                      clay particles with strong paracrystalline order and refers
                      to a chemical potential/distance dependence. The
                      thermodynamic model assumes a bidisperse distance
                      distribution and gives input to the scattering model.
                      Experimentally, polymer/clay systems with many molecular
                      polymer masses were studied showing all very similar
                      scattering curves. While the dominating bulk phase shows
                      only the same weak tendency to stack formation for all
                      molecular polymer masses, one coexisting phase with stronger
                      stack formation was identified. The latter sample was used
                      to determine the thickness of the clay platelets with
                      adsorbed polymer that was then used to model the dominating
                      bulk phase. The comparisons to the theory revealed that (a)
                      most polymers are tightly bound to the clay, and (b) an
                      agreement between the modeling and the theory was achieved.
                      The main result of the experiments is the fraction of free
                      polymers of 1:2400 that are not tightly bound to the clay
                      particles.},
      cin          = {JCNS-FRM-II / JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
                      G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)External-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:30836259},
      UT           = {WOS:000463310100018},
      doi          = {10.1016/j.jcis.2019.02.091},
      url          = {https://juser.fz-juelich.de/record/861201},
}