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@ARTICLE{Murmann:861261,
      author       = {Murmann, Patrick and von Aspern, Natascha and Janssen, Pia
                      and Kalinovich, Nataliya and Shevchuk, Michael and
                      Röschenthaler, Gerd-Volker and Winter, Martin and
                      Cekic-Laskovic, Isidora},
      title        = {{I}nfluence of the {F}luorination {D}egree of
                      {O}rganophosphates on {F}lammability and {E}lectrochemical
                      {P}erformance in {L}ithium {I}on {B}atteries},
      journal      = {Journal of the Electrochemical Society},
      volume       = {165},
      number       = {9},
      issn         = {1945-7111},
      address      = {Pennington, NJ},
      publisher    = {Electrochemical Soc.},
      reportid     = {FZJ-2019-01765},
      pages        = {A1935 - A1942},
      year         = {2018},
      abstract     = {Four symmetric compounds deriving from the alkyl chain
                      containing tripropyl phosphate were designed and synthesized
                      by varying substitution of fluorine in the side chains and
                      added as co-solvents to yield $10\%,$ $20\%$ and $30\%$
                      concentrated electrolyte formulations. The formulated
                      electrolytes were physicochemically and electrochemically
                      characterized and compared to a state-of-the-art organic
                      carbonate-based electrolyte in regard to the flammability as
                      well as any occurring trade-off in cycling performance. The
                      addition of phosphates resulted in superior flammability
                      behavior of the electrolyte as the flammability could be
                      severely reduced with increased concentration of the
                      phosphates. As the addition of such phosphate compounds to
                      the electrolyte usually comes with a trade-off in cycling
                      performance, electrochemical behavior was thoroughly
                      investigated regarding ionic conductivity, anodic stability
                      limit and cycling stability in lithium metal and lithium ion
                      cells. The influence of the varying fluorine content as well
                      as position of the substituted fluorine was determined and
                      discussed. The tripropyl phosphate derivatives showed very
                      promising cycling results hand in hand with a significant
                      improvement achieved regarding the flammability of the
                      electrolyte.},
      cin          = {IEK-12},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000440924800047},
      doi          = {10.1149/2.0011810jes},
      url          = {https://juser.fz-juelich.de/record/861261},
}