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000861643 1001_ $$0P:(DE-HGF)0$$aYorov, Kh. E.$$b0
000861643 245__ $$aPhotoluminescent porous aerogel monoliths containing ZnEu-complex: the first example of aerogel modified with a heteronuclear metal complex
000861643 260__ $$aDordrecht [u.a.]$$bSpringer Science + Business Media B.V$$c2019
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000861643 520__ $$aA procedure for the chemical immobilization of a new ZnII–EuIII heterobimetallic complex in the SiO2 aerogel matrix has been developed. In this Zn–Eu complex, a peripheral non-luminescent Zn ion acts as a binder to a silica matrix and prevents direct interaction of rare-earth ions with OH− and NH− groups in the silica matrix, which would have a detrimental effect on the luminescence of lanthanides. The procedure includes the synthesis of complexes, co-gelation of the obtained complex with SiO2 sol, the washing of lyogels, and their subsequent supercritical drying in CO2. The composition and properties of the obtained aerogels were investigated using a low-temperature nitrogen adsorption technique, helium pycnometry, FTIR, Raman, UV–visible, and luminescence spectroscopy, XPS, PXRD, SEM, TEM, TGA combined with mass spectrometry, and small-angle neutron scattering. The aerogels modified with the ZnII–EuIII complex demonstrated strong red luminescence upon excitation with UV light.
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000861643 7001_ $$0P:(DE-HGF)0$$aKottsov, S. Yu.$$b1
000861643 7001_ $$0P:(DE-HGF)0$$aBaranchikov, А. Е.$$b2
000861643 7001_ $$0P:(DE-HGF)0$$aBoytsova, O. V.$$b3
000861643 7001_ $$0P:(DE-HGF)0$$aKiskin, M. A.$$b4
000861643 7001_ $$0P:(DE-HGF)0$$aVaraksina, E. A.$$b5
000861643 7001_ $$0P:(DE-HGF)0$$aKopitsa, G. P.$$b6
000861643 7001_ $$0P:(DE-HGF)0$$aLermontov, S. А.$$b7
000861643 7001_ $$0P:(DE-HGF)0$$aSidorov, A. A.$$b8
000861643 7001_ $$0P:(DE-Juel1)130893$$aPipich, V.$$b9
000861643 7001_ $$0P:(DE-HGF)0$$aLen, A.$$b10
000861643 7001_ $$0P:(DE-HGF)0$$aAgafonov, A. V.$$b11
000861643 7001_ $$0P:(DE-HGF)0$$aIvanov, V. K.$$b12$$eCorresponding author
000861643 773__ $$0PERI:(DE-600)1472726-2$$a10.1007/s10971-019-04958-9$$p304–318$$tJournal of sol gel science and technology$$v92$$x1573-4846$$y2019
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