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@ARTICLE{Yorov:861643,
      author       = {Yorov, Kh. E. and Kottsov, S. Yu. and Baranchikov, А. Е.
                      and Boytsova, O. V. and Kiskin, M. A. and Varaksina, E. A.
                      and Kopitsa, G. P. and Lermontov, S. А. and Sidorov, A. A.
                      and Pipich, V. and Len, A. and Agafonov, A. V. and Ivanov,
                      V. K.},
      title        = {{P}hotoluminescent porous aerogel monoliths containing
                      {Z}n{E}u-complex: the first example of aerogel modified with
                      a heteronuclear metal complex},
      journal      = {Journal of sol gel science and technology},
      volume       = {92},
      issn         = {1573-4846},
      address      = {Dordrecht [u.a.]},
      publisher    = {Springer Science + Business Media B.V},
      reportid     = {FZJ-2019-02089},
      pages        = {304–318},
      year         = {2019},
      abstract     = {A procedure for the chemical immobilization of a new
                      ZnII–EuIII heterobimetallic complex in the SiO2 aerogel
                      matrix has been developed. In this Zn–Eu complex, a
                      peripheral non-luminescent Zn ion acts as a binder to a
                      silica matrix and prevents direct interaction of rare-earth
                      ions with OH− and NH− groups in the silica matrix, which
                      would have a detrimental effect on the luminescence of
                      lanthanides. The procedure includes the synthesis of
                      complexes, co-gelation of the obtained complex with SiO2
                      sol, the washing of lyogels, and their subsequent
                      supercritical drying in CO2. The composition and properties
                      of the obtained aerogels were investigated using a
                      low-temperature nitrogen adsorption technique, helium
                      pycnometry, FTIR, Raman, UV–visible, and luminescence
                      spectroscopy, XPS, PXRD, SEM, TEM, TGA combined with mass
                      spectrometry, and small-angle neutron scattering. The
                      aerogels modified with the ZnII–EuIII complex demonstrated
                      strong red luminescence upon excitation with UV light.},
      cin          = {JCNS-FRM-II / JCNS-1 / MLZ},
      ddc          = {670},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-588b)4597118-3},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS3-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000492424200007},
      doi          = {10.1007/s10971-019-04958-9},
      url          = {https://juser.fz-juelich.de/record/861643},
}