Hauptseite > Publikationsdatenbank > Photoluminescent porous aerogel monoliths containing ZnEu-complex: the first example of aerogel modified with a heteronuclear metal complex > print

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024 7 _ |a 1573-4846
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037 _ _ |a FZJ-2019-02089
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100 1 _ |a Yorov, Kh. E.
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245 _ _ |a Photoluminescent porous aerogel monoliths containing ZnEu-complex: the first example of aerogel modified with a heteronuclear metal complex
260 _ _ |a Dordrecht [u.a.]
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520 _ _ |a A procedure for the chemical immobilization of a new ZnII–EuIII heterobimetallic complex in the SiO2 aerogel matrix has been developed. In this Zn–Eu complex, a peripheral non-luminescent Zn ion acts as a binder to a silica matrix and prevents direct interaction of rare-earth ions with OH− and NH− groups in the silica matrix, which would have a detrimental effect on the luminescence of lanthanides. The procedure includes the synthesis of complexes, co-gelation of the obtained complex with SiO2 sol, the washing of lyogels, and their subsequent supercritical drying in CO2. The composition and properties of the obtained aerogels were investigated using a low-temperature nitrogen adsorption technique, helium pycnometry, FTIR, Raman, UV–visible, and luminescence spectroscopy, XPS, PXRD, SEM, TEM, TGA combined with mass spectrometry, and small-angle neutron scattering. The aerogels modified with the ZnII–EuIII complex demonstrated strong red luminescence upon excitation with UV light.
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700 1 _ |a Kottsov, S. Yu.
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700 1 _ |a Baranchikov, А. Е.
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700 1 _ |a Boytsova, O. V.
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700 1 _ |a Kiskin, M. A.
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700 1 _ |a Varaksina, E. A.
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700 1 _ |a Kopitsa, G. P.
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700 1 _ |a Lermontov, S. А.
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700 1 _ |a Sidorov, A. A.
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700 1 _ |a Pipich, V.
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700 1 _ |a Len, A.
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700 1 _ |a Agafonov, A. V.
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700 1 _ |a Ivanov, V. K.
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773 _ _ |a 10.1007/s10971-019-04958-9
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