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@ARTICLE{SchulzeLammers:862517,
author = {Schulze Lammers, Bertram and Ebeling, René and Dirksen,
Elena and Müller, Thomas J. J. and Karthäuser, Silvia},
title = {{C}omplex {A}dsorption {B}ehavior of a {N}onplanar
{N}aphthalene {D}iimide on {A}u(111)},
journal = {The journal of physical chemistry / C C, Nanomaterials and
interfaces},
volume = {123},
number = {15},
issn = {1932-7455},
address = {Washington, DC},
publisher = {Soc.66306},
reportid = {FZJ-2019-02820},
pages = {9860 - 9867},
year = {2019},
abstract = {Naphthalene diimide (NDI) derivatives are extensively
studied in the field of supramolecular and materials
chemistry due to their versatility in coordination, electron
deficiency, and planar aromatic core. Here, we report on the
self-assembly behavior and the electronic properties of
2,7-dibenzyl-1,4,5,8-naphthalenetetracarboxylic diimide
(BNTCDI) studied by low-temperature scanning tunneling
microscopy. BNTCDI adsorbed on Au(111) is highly mobile and
reveals a tendency to form chain structures on the step
edges at low coverages. The chains are kept together by
intermolecular hydrogen bonds between neighboring NDI
backbones. Within the chain structures, the orbital
appearance of single molecules was clearly identified.
Additionally, supramolecular structures consisting of
ordered double layers were observed on terraces for higher
surface coverages. The molecule–substrate interaction is
investigated in detail via scanning tunneling spectroscopy
for different molecular arrangements. The results reveal
distinct insights into the subtle balance between
intermolecular and interface interactions determining the
self-assembly behavior of BNTCDI resulting in chain
structures at step edges and ordered double layers on
Au(111) terraces.},
cin = {PGI-7 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)PGI-7-20110106 / $I:(DE-82)080009_20140620$},
pnm = {524 - Controlling Collective States (POF3-524)},
pid = {G:(DE-HGF)POF3-524},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000465488600025},
doi = {10.1021/acs.jpcc.9b00554},
url = {https://juser.fz-juelich.de/record/862517},
}