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@ARTICLE{Rodenbcher:862612,
      author       = {Rodenbücher, Christian and Wippermann, Klaus and Korte,
                      Carsten},
      title        = {{A}tomic {F}orce {S}pectroscopy on {I}onic {L}iquids},
      journal      = {Applied Sciences},
      volume       = {9},
      number       = {11},
      issn         = {2076-3417},
      address      = {Basel},
      publisher    = {MDPI},
      reportid     = {FZJ-2019-02881},
      pages        = {2207 -},
      year         = {2019},
      abstract     = {Ionic liquids have become of significant relevance in
                      chemistry, as they can serve as environmentally-friendly
                      solvents, electrolytes, and lubricants with bespoke
                      properties. In particular for electrochemical applications,
                      an understanding of the interface structure between the
                      ionic liquid and an electrified interface is needed to model
                      and optimize the reactions taking place on the solid
                      surface. As with ionic liquids, the interplay between
                      electrostatic forces and steric effects leads to an
                      intrinsic heterogeneity, as the structure of the ionic
                      liquid above an electrified interface cannot be described by
                      the classical electrical double layer model. Instead, a
                      layered solvation layer is present with a structure that
                      depends on the material combination of the ionic liquid and
                      substrate. In order to experimentally monitor this
                      structure, atomic force spectroscopy (AFS) has become the
                      method of choice. By measuring the force acting on a sharp
                      microfabricated tip while approaching the surface in an
                      ionic liquid, it has become possible to map the solvation
                      layers with sub-nanometer resolution. In this review, we
                      provide an overview of the AFS studies on ionic liquids
                      published in recent years that illustrate how the interface
                      is formed and how it can be modified by applying electrical
                      potential or by adding impurities and solvents},
      cin          = {IEK-3},
      ddc          = {600},
      cid          = {I:(DE-Juel1)IEK-3-20101013},
      pnm          = {135 - Fuel Cells (POF3-135)},
      pid          = {G:(DE-HGF)POF3-135},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000472641200035},
      doi          = {10.3390/app9112207},
      url          = {https://juser.fz-juelich.de/record/862612},
}