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@ARTICLE{Dash:862737,
author = {Dash, Apurv and Vaßen, Robert and Guillon, Olivier and
Gonzalez-Julian, Jesus},
title = {{M}olten salt shielded synthesis of oxidation prone
materials in air},
journal = {Nature materials},
volume = {18},
number = {5},
issn = {1476-4660},
address = {Basingstoke},
publisher = {Nature Publishing Group},
reportid = {FZJ-2019-02979},
pages = {465 - 470},
year = {2019},
abstract = {To prevent spontaneous oxidation during the
high-temperature synthesis of non-oxide ceramics, an inert
atmosphere is conventionally required1,2. This, however,
results in high energy demand and high production costs.
Here, we present a process for the synthesis and
consolidation of oxidation-prone materials, the ‘molten
salt shielded synthesis/sintering’ process (MS3), which
uses molten salts as a reaction medium and also to protect
the ceramic powders from oxidation during high-temperature
processing in air. Synthesis temperatures are also reduced,
and the final product is a highly pure, fine and loose
powder that does not require additional milling steps. MS3
has been used for the synthesis of different ternary
transition metal compounds (MAX phases, such as Ti3SiC23,
Ti2AlN4, MoAlB5), binary carbides (TiC) and for the
sintering of titanium. The availability of high-quality
powders, combined with energy and cost savings, may remove
one of the bottlenecks for the industrial application of
these materials.},
cin = {IEK-1 / JARA-ENERGY},
ddc = {610},
cid = {I:(DE-Juel1)IEK-1-20101013 / $I:(DE-82)080011_20140620$},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30936480},
UT = {WOS:000465199900017},
doi = {10.1038/s41563-019-0328-1},
url = {https://juser.fz-juelich.de/record/862737},
}