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@ARTICLE{Miao:862887,
author = {Miao, Ping and Wang, Rui and Zhu, Weiming and Liu, Jiajie
and Liu, Tongchao and Hu, Jiangtao and Li, Shuankui and Tan,
Zhijian and Koda, Akihiro and Zhu, Fengfeng and Feng, Erxi
and Su, Yixi and Kamiyama, Takashi and Xiao, Yinguo and Pan,
Feng},
title = {{R}evealing magnetic ground state of a layered cathode
material by muon spin relaxation and neutron scattering
experiments},
journal = {Applied physics letters},
volume = {114},
number = {20},
issn = {1077-3118},
address = {Melville, NY},
publisher = {American Inst. of Physics},
reportid = {FZJ-2019-03070},
pages = {203901 -},
year = {2019},
abstract = {Although the majority of studies on battery materials have
focused on enhancing their electrochemical performance, the
understanding of their magnetic and atomic structures as
well as the intimate connections between these structures
and properties is significant. Muon spin relaxation (μSR)
spectroscopy and neutron scattering techniques at low
temperature have been used to explore the nature of the
magnetic state of Li(Ni0.4Mn0.4Co0.2)O2 cathode materials.
Interestingly, the μSR experiment reveals that the spins of
Ni/Mn/Co ions turn glassy at a low temperature of 19 K,
while the unprecedented spin dynamics survives until the
base temperature of 5.6 K. Moreover, the complementary
neutron scattering measurements show magnetic diffuse
scattering signals in the form of a broad peak at
Q = 1.6 Å−1 attributed to short-range spin
correlation which establishes below ∼120 K. Upon cooling
to as low as 480 mK, long-range magnetic order still could
not be established. The inelastic neutron scattering
intensities demonstrate clearly the existence of dynamic
spin fluctuations. In contrast to the conventional spin
glass system, the coexistence of both dynamic and static
components in the ground state suggests an unconventional
spin glass state in magnetically frustrated
Li(Ni0.4Mn0.4Co0.2)O2 cathode materials for Li-ion
batteries.},
cin = {JCNS-FRM-II},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218},
pnm = {6212 - Quantum Condensed Matter: Magnetism,
Superconductivity (POF3-621) / 6G15 - FRM II / MLZ
(POF3-6G15) / 6G4 - Jülich Centre for Neutron Research
(JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6212 / G:(DE-HGF)POF3-6G15 /
G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)DNS-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000470153700020},
doi = {10.1063/1.5096620},
url = {https://juser.fz-juelich.de/record/862887},
}