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@PHDTHESIS{Jeong:862940,
      author       = {Jeong, Hyeondeok},
      title        = {{C}oupling a {S}olid {O}xide {F}uel {C}ell with a {B}iomass
                      {G}asifier: {D}egradation {M}echanisms and {A}lternative
                      {A}node {M}aterials},
      volume       = {460},
      school       = {RWTH Aachen University},
      type         = {Dissertation},
      address      = {Jülich},
      publisher    = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
      reportid     = {FZJ-2019-03101},
      isbn         = {978-3-95806-398-3},
      series       = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
                      Umwelt / Energy $\&$ Environment},
      pages        = {II, 112},
      year         = {2019},
      note         = {Dissertation, RWTH Aachen University, 2019},
      abstract     = {Anode-supported solid oxide fuel cells (SOFCs) with a
                      state-of-the-art Ni/YSZ anode have been tested insimulated
                      bio-syngas with controlled addition of tars and sulfur as
                      model molecules to study the influenceof impurities on the
                      degradation of SOFCs. The phenol tar causes macro- and
                      micro-scale structuralchanges in the support including
                      erosion, Ni coarsening, and carbon fiber formation. However,
                      the effect of phenol on the cell performance was not
                      pronounced below a content of 8 g/Nm$^{3}$ in the few
                      hundreds of hour test period. On the other hand, the cell
                      responded immediately after 0.5 g/Nm$^{3}$ of naphthalene
                      were added in the fuel. There was no microstructure change
                      and the carbon deposition was found only on thesurface of
                      the support. A stack test with real bio-syngas derived from
                      wood pellets showed more practical problems. The stack
                      showed considerable performance degradation and the test was
                      stopped after 5 hours of operation due to an increase of the
                      pressure drop. There were heavy carbon depositions at the
                      support surface and the Ni mesh current collector. The
                      microstructure change of support was also observed near and
                      under the carbon deposition area, and the Ni metal dusting
                      behavior was observed from the Ni particles in support and
                      Ni mesh current collector. ...},
      cin          = {IEK-1},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {899 - ohne Topic (POF3-899)},
      pid          = {G:(DE-HGF)POF3-899},
      typ          = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
      url          = {https://juser.fz-juelich.de/record/862940},
}