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@ARTICLE{Kazemi:863002,
author = {Kazemi, Namdar and Danilov, Dmitri L. and Haverkate, Lucas
and Dudney, Nancy J. and Unnikrishnan, Sandeep and Notten,
Peter H. L.},
title = {{M}odeling of all-solid-state thin-film {L}i-ion batteries:
{A}ccuracy improvement},
journal = {Solid state ionics},
volume = {334},
issn = {0167-2738},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2019-03149},
pages = {111 - 116},
year = {2019},
abstract = {Thin-film Solid-State Batteries (TFSSB) is one of most
promising and quickly developing fields in modern
electrochemical energy storage. Modeling these devices is
interesting from theoretical and practical point of view.
This paper represents a simulation approach for TFSSB which
overcome a major drawback of available mathematical models,
i.e. decline in accuracy of the models at high current
rates. A one-dimensional electrochemical model, including
charge transfer kinetics on the electrolyte-electrode
interface, diffusion and migration in electrolyte as well as
diffusion in intercalation electrode has been developed and
the simulation results are compared to experimental
voltage-capacity measurements. A new definition of diffusion
coefficient as a function of concentration, based on the
experimental measurements, is used to improve the
performance of the model. The simulation results fit the
available experimental data at low and high discharge
currents up to 5 mA cm−2. The models show that the cathode
diffusion constant is a prime factor limiting the rate
capability for TFSSB in particular for ultrafast charging
applications.},
cin = {IEK-9},
ddc = {530},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000463981900018},
doi = {10.1016/j.ssi.2019.02.003},
url = {https://juser.fz-juelich.de/record/863002},
}