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@ARTICLE{Scotti:863186,
      author       = {Scotti, Andrea and Denton, Alan R. and Brugnoni, Monia and
                      Houston, Judith E. and Schweins, Ralf and Potemkin, Igor I.
                      and Richtering, Walter},
      title        = {{D}eswelling of {M}icrogels in {C}rowded {S}uspensions
                      {D}epends on {C}ross-{L}ink {D}ensity and {A}rchitecture},
      journal      = {Macromolecules},
      volume       = {52},
      number       = {11},
      issn         = {1520-5835},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2019-03281},
      pages        = {3995 - 4007},
      year         = {2019},
      abstract     = {Microgels are nanometer-to-micrometer-sized cross-linked
                      polymer networks that swell when dispersed in a good
                      solvent. These soft colloids have emerged as versatile
                      building blocks of smart materials, which are distinguished
                      by their unique ability to adapt their behavior to changes
                      in external stimuli. Using X-ray and neutron scattering and
                      molecular simulation methods, we systematically measured and
                      modeled the response to crowding of compressible, deformable
                      microgels with varying cross-link densities and internal
                      architectures. Our experiments and simulations demonstrate
                      that incorporating a solvent-filled cavity during chemical
                      synthesis provides an independent means of controlling
                      microgel swelling that complements the influence of changing
                      cross-link density. In other words, knowledge of the content
                      of cross-links alone cannot be used to define microgel
                      softness, but microgel architecture is another key property
                      that affects softness. These results are potentially
                      important for biomedical applications, such as drug delivery
                      and biosensing.},
      cin          = {JCNS-FRM-II / MLZ},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000471729000004},
      doi          = {10.1021/acs.macromol.9b00729},
      url          = {https://juser.fz-juelich.de/record/863186},
}