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000863480 1001_ $$0P:(DE-Juel1)165181$$aYang, Xiaosheng$$b0
000863480 245__ $$aIdentifying surface reaction intermediates with photoemission tomography
000863480 260__ $$a[London]$$bNature Publishing Group UK$$c2019
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000863480 520__ $$aThe determination of reaction pathways and the identification of reaction intermediates are key issues in chemistry. Surface reactions are particularly challenging, since many methods of analytical chemistry are inapplicable at surfaces. Recently, atomic force microscopy has been employed to identify surface reaction intermediates. While providing an excellent insight into the molecular backbone structure, atomic force microscopy is less conclusive about the molecular periphery, where adsorbates tend to react with the substrate. Here we show that photoemission tomography is extremely sensitive to the character of the frontier orbitals. Specifically, hydrogen abstraction at the molecular periphery is easily detected, and the precise nature of the reaction intermediates can be determined. This is illustrated with the thermally induced reaction of dibromo-bianthracene to graphene which is shown to proceed via a fully hydrogenated bisanthene intermediate. We anticipate that photoemission tomography will become a powerful companion to other techniques in the study of surface reaction pathways.
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000863480 7001_ $$0P:(DE-HGF)0$$aEgger, Larissa$$b1
000863480 7001_ $$0P:(DE-HGF)0$$aHurdax, Philipp$$b2
000863480 7001_ $$00000-0001-6717-9752$$aKaser, Hendrik$$b3
000863480 7001_ $$00000-0001-8883-0495$$aLüftner, Daniel$$b4
000863480 7001_ $$0P:(DE-Juel1)167128$$aBocquet, François C.$$b5
000863480 7001_ $$00000-0001-7741-2394$$aKoller, Georg$$b6
000863480 7001_ $$00000-0003-2810-7419$$aGottwald, Alexander$$b7
000863480 7001_ $$00000-0002-5071-9385$$aTegeder, Petra$$b8
000863480 7001_ $$00000-0001-8252-8869$$aRichter, Mathias$$b9
000863480 7001_ $$0P:(DE-HGF)0$$aRamsey, Michael G.$$b10
000863480 7001_ $$00000-0002-8057-7795$$aPuschnig, Peter$$b11
000863480 7001_ $$0P:(DE-Juel1)128790$$aSoubatch, Serguei$$b12$$eCorresponding author
000863480 7001_ $$0P:(DE-Juel1)128791$$aTautz, F. Stefan$$b13
000863480 773__ $$0PERI:(DE-600)2553671-0$$a10.1038/s41467-019-11133-9$$gVol. 10, no. 1, p. 3189$$n1$$p3189$$tNature Communications$$v10$$x2041-1723$$y2019
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