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000863501 1001_ $$0P:(DE-HGF)0$$aTorres, Juliana A.$$b0
000863501 245__ $$aEnhancing TiO2 Activity for CO2 Photoreduction through MgO Decoration
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000863501 520__ $$aHerein we report on the influence of MgO’s basic character in the photoactivity of MgO:TiO2 nanocomposites for the CO2 reduction reaction. TiO2 nanoparticles, decorated with MgO in different mass proportions, were synthesized by the physical mixing of pre-synthesized oxides followed by calcination. The decorated samples presented enhanced photocatalytic activity with higher selectivity for CO, while CH4 was also produced, as well as HCOOH and CH3COOH in a liquid medium in lower proportions. The results indicate that the beneficial MgO influence is only effective at low amounts, whilst a high MgO amount favors an insulating behavior instead of semiconducting, reducing the nanocomposite performance for CO2 photoreduction.
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000863501 7001_ $$0P:(DE-HGF)0$$aNogueira, André E.$$b1
000863501 7001_ $$0P:(DE-HGF)0$$ada Silva, Gelson T. S. T.$$b2
000863501 7001_ $$0P:(DE-HGF)0$$aLopes, Osmando F.$$b3
000863501 7001_ $$0P:(DE-HGF)0$$aWang, Yanjie$$b4
000863501 7001_ $$0P:(DE-HGF)0$$aHe, Tao$$b5
000863501 7001_ $$0P:(DE-Juel1)177079$$aRibeiro de Oliveira, Caue$$b6$$eCorresponding author
000863501 773__ $$0PERI:(DE-600)2710038-8$$a10.1016/j.jcou.2019.09.008$$gVol. 35, p. 106 - 114$$p106 - 114$$tJournal of CO2 utilization$$v35$$x2212-9820$$y2020
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