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100 1 _ |a Torres, Juliana A.
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245 _ _ |a Enhancing TiO2 Activity for CO2 Photoreduction through MgO Decoration
260 _ _ |a Amsterdam ˜[u.a.]œ
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520 _ _ |a Herein we report on the influence of MgO’s basic character in the photoactivity of MgO:TiO2 nanocomposites for the CO2 reduction reaction. TiO2 nanoparticles, decorated with MgO in different mass proportions, were synthesized by the physical mixing of pre-synthesized oxides followed by calcination. The decorated samples presented enhanced photocatalytic activity with higher selectivity for CO, while CH4 was also produced, as well as HCOOH and CH3COOH in a liquid medium in lower proportions. The results indicate that the beneficial MgO influence is only effective at low amounts, whilst a high MgO amount favors an insulating behavior instead of semiconducting, reducing the nanocomposite performance for CO2 photoreduction.
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700 1 _ |a Nogueira, André E.
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700 1 _ |a da Silva, Gelson T. S. T.
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700 1 _ |a Lopes, Osmando F.
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700 1 _ |a Wang, Yanjie
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700 1 _ |a He, Tao
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700 1 _ |a Ribeiro de Oliveira, Caue
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773 _ _ |a 10.1016/j.jcou.2019.09.008
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|t Journal of CO2 utilization
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856 4 _ |y Published on 2019-10-29. Available in OpenAccess from 2021-10-29.
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856 4 _ |y Published on 2019-10-29. Available in OpenAccess from 2021-10-29.
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