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000863767 1001_ $$0P:(DE-Juel1)176662$$aBjelcic, Monika$$b0
000863767 245__ $$aCorrelation between thermophoretic behavior and hydrophilicity for various alcohols⋆
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000863767 520__ $$aRecent experiments for various amides and sugars showed a clear correlation of the temperature dependence of the Soret coefficient with the hydrophilicity, quantitatively described by the logarithm of the 1-octanol/water partition coefficient $\log P$. This coefficient is a measure for the hydrophilicity/hydrophobicity balance of a solute and is often used to model the transport of a compound in the environment or to screen for potential pharmaceutical compounds. In order to validate whether this concept works also for other water soluble molecules we investigated systematically the thermophoresis of mono- and poly hydric alcohols. As experimental method we use a holographic grating technique called infrared Thermal Diffusion Forced Rayleigh Scattering (IR-TDFRS). Experiments showed that the temperature dependence of the Soret coefficient of polyhydric alcohols also correlates with $\log P$ and lies on the same master plot as amides and sugars.
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000863767 7001_ $$0P:(DE-Juel1)166572$$aNiether, Doreen$$b1$$ufzj
000863767 7001_ $$0P:(DE-Juel1)131034$$aWiegand, Simone$$b2$$eCorresponding author
000863767 773__ $$0PERI:(DE-600)2004003-9$$a10.1140/epje/i2019-11831-x$$gVol. 42, no. 5, p. 68$$n5$$p68$$tThe European physical journal / E Soft matter E$$v42$$x1292-895X$$y2019
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000863767 8564_ $$uhttps://juser.fz-juelich.de/record/863767/files/alcohols015.pdf$$yPublished on 2019-05-31. Available in OpenAccess from 2020-05-31.
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