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@ARTICLE{Bjelcic:863767,
author = {Bjelcic, Monika and Niether, Doreen and Wiegand, Simone},
title = {{C}orrelation between thermophoretic behavior and
hydrophilicity for various alcohols⋆},
journal = {The European physical journal / E Soft matter E},
volume = {42},
number = {5},
issn = {1292-895X},
address = {Heidelberg},
publisher = {Springer},
reportid = {FZJ-2019-03764},
pages = {68},
year = {2019},
abstract = {Recent experiments for various amides and sugars showed a
clear correlation of the temperature dependence of the Soret
coefficient with the hydrophilicity, quantitatively
described by the logarithm of the 1-octanol/water partition
coefficient $\log P$. This coefficient is a measure for the
hydrophilicity/hydrophobicity balance of a solute and is
often used to model the transport of a compound in the
environment or to screen for potential pharmaceutical
compounds. In order to validate whether this concept works
also for other water soluble molecules we investigated
systematically the thermophoresis of mono- and poly hydric
alcohols. As experimental method we use a holographic
grating technique called infrared Thermal Diffusion Forced
Rayleigh Scattering (IR-TDFRS). Experiments showed that the
temperature dependence of the Soret coefficient of
polyhydric alcohols also correlates with $\log P$ and lies
on the same master plot as amides and sugars.},
cin = {ICS-3},
ddc = {530},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551)},
pid = {G:(DE-HGF)POF3-551},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:31144058},
UT = {WOS:000469518400001},
doi = {10.1140/epje/i2019-11831-x},
url = {https://juser.fz-juelich.de/record/863767},
}