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@ARTICLE{Lefler:863858,
author = {Lefler, Benjamin M. and Duchon, Tomas and Karapetrov, Goran
and Wang, Jiayi and Schneider, Claus M. and May, Steven J.},
title = {{R}econfigurable lateral anionic heterostructures in oxide
thin films via lithographically defined topochemistry},
journal = {Physical review materials},
volume = {3},
number = {7},
issn = {2475-9953},
address = {College Park, MD},
publisher = {APS},
reportid = {FZJ-2019-03829},
pages = {073802},
year = {2019},
abstract = {Laterally structured materials can exhibit properties
uniquely suited for applications in electronics,
magnetoelectric memory, photonics, and nanoionics. Here, a
patterning approach is presented that combines the precise
geometric control enabled by lithography with topochemical
anionic manipulation of complex oxide films. Utilizing
oxidation and fluorination reactions, striped patterns of
SrFeO2.5/SrFeO3,SrFeO2.5/SrFeO2F, and SrFeO3/SrFeO2F have
been prepared with lateral periodicities of 200, 20, and 4
μm. Coexistence of the distinct chemical phases is
confirmed through x-ray diffraction, optical and
photoemission microscopies, and optical spectroscopy. The
lateral heterostructures exhibit highly anisotropic
electronic transport and also enable transience and
regeneration of patterns through reversible redox reactions.
This approach can be broadly applied to a variety of
metal-oxide systems, enabling chemically reconfigurable
lateral heterostructures tailored for specific electronic,
optical, ionic, thermal, or magnetic functionalities.},
cin = {PGI-6},
ddc = {530},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000474390900002},
doi = {10.1103/PhysRevMaterials.3.073802},
url = {https://juser.fz-juelich.de/record/863858},
}