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@ARTICLE{Horsthemke:864040,
author = {Horsthemke, Fabian and Winkler, Volker and Diehl, Marcel
and Winter, Martin and Nowak, Sascha},
title = {{C}oncept for the {A}nalysis of the {E}lectrolyte
{C}omposition within the {C}ell {M}anufacturing {P}rocess:
{F}rom {S}ealing to {S}ample {P}reparation},
journal = {Energy technology},
volume = {8},
number = {2},
issn = {2194-4296},
address = {Weinheim [u.a.]},
publisher = {Wiley-VCH},
reportid = {FZJ-2019-03956},
pages = {1801081},
year = {2020},
abstract = {Lithium‐ion battery (LIB) cells of the 18650 format are
built in‐house with different amounts of an electrolyte.
After wetting and prior to subsequent formation, the cells
are opened. The electrolyte is regained by centrifuging the
entire jelly roll and quantified by a gas
chromatography‐flame ionization detector (GC‐FID) and
inductively coupled plasma‐optical emission spectroscopy
(ICP‐OES). The influence of a filling protocol applying
cycles with over‐ and reduced pressure is examined with a
focus on the electrolyte composition. No significant
difference is found in the ratio of linear (LC) to cyclic
carbonates (CCs). Furthermore, extraction by centrifugation
is investigated in different scenarios by simulating almost
“dry” cells to minimize alterations during the sample
preparation. The quantification of these electrolytes
indicates a slightly reduced amount of LC in the sample.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000511910200013},
doi = {10.1002/ente.201801081},
url = {https://juser.fz-juelich.de/record/864040},
}