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@ARTICLE{Gao:864120,
author = {Gao, Z. and Haegel, F.-H. and Esser, O. and Zimmermann,
Egon and Vereecken, H. and Huisman, J. A.},
title = {{S}pectral {I}nduced {P}olarization of {B}iochar in
{V}ariably {S}aturated {S}oil},
journal = {Vadose zone journal},
volume = {18},
number = {1},
issn = {1539-1663},
address = {Alexandria, Va.},
publisher = {GeoScienceWorld},
reportid = {FZJ-2019-04017},
pages = {},
year = {2019},
abstract = {Biochar is considered a promising soil amendment, but an
effective method to detect and characterize the spatial
distribution and temporal dynamics of biochar in soil is
still missing. The aim of this study is to investigate the
ability of the spectral induced polarization (SIP) method
for the noninvasive detection of biochar in unsaturated
sandy media. In particular, a pure sand and two
sand–biochar mixtures with 1 and $2\%$ biochar made from
pine (Pinus spp.) wood by pyrolysis at 800°C were
investigated. The measured SIP spectra as a function of
saturation were interpreted by fitting a Cole–Cole model
to the low-frequency part of the SIP measurements. The
porous nature of the biochar particles strongly affected the
SIP response of the partially saturated sand–biochar
mixtures. Due to the high residual water content of the
biochar in a dry background, the relationship between bulk
electrical conductivity and water saturation was nonlinear
in a log–log representation. This nonlinear behavior could
adequately be explained with a dielectric mixing model that
considered the drainage of the biochar particles. Both the
measured phase and chargeability of the sand–biochar
mixtures showed a complex dependence on water saturation.
This was attributed to the decrease in polarization strength
of the biochar particles with desaturation and the
simultaneous increase in phase of the sand background.
Overall, the results of this study suggest that field SIP
measurements may be a promising tool for the
characterization and monitoring of biochar amendments to
agricultural soils.},
cin = {IBG-3 / ZEA-2},
ddc = {550},
cid = {I:(DE-Juel1)IBG-3-20101118 / I:(DE-Juel1)ZEA-2-20090406},
pnm = {255 - Terrestrial Systems: From Observation to Prediction
(POF3-255)},
pid = {G:(DE-HGF)POF3-255},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000480303900001},
doi = {10.2136/vzj2018.12.0213},
url = {https://juser.fz-juelich.de/record/864120},
}