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@ARTICLE{Thaler:864177,
      author       = {Thaler, Florian and Udomsilp, David and Schafbauer,
                      Wolfgang and Bischof, Cornelia and Fukuyama, Yosuke and
                      Miura, Yohei and Kawabuchi, Mari and Taniguchi, Shunsuke and
                      Takemiya, Satoshi and Nenning, Andreas and Opitz, Alexander
                      K. and Bram, Martin},
      title        = {{R}edox stability of metal-supported fuel cells with
                      nickel/gadolinium-doped ceria anode},
      journal      = {Journal of power sources},
      volume       = {434},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2019-04042},
      pages        = {226751, 9 pages},
      year         = {2019},
      abstract     = {Metal-supported fuel cells (MSCs) are promising candidates
                      for not only stationary but also mobile applications. Their
                      appeal is in their potential to withstand reoxidation of the
                      anode, which might occur by an interruption of the fuel
                      supply or an emergency shutdown of the fuel cell system. A
                      novel nickel/gadolinium-doped ceria anode (Ni/GDC) was
                      recently introduced in a MSC concept of Plansee, almost
                      doubling power density compared to cells with a
                      nickel/yttria-doped zirconia (Ni/YSZ) anode. In this study,
                      both cell concepts are compared concerning their ability to
                      tolerate harsh redox cycles. Therefore, controlled redox
                      cycles of the anodes were conducted at different
                      temperatures. The response of the cell’s power output to
                      the redox cycling experiments was continuously recorded. In
                      the case of MSCs with a Ni/YSZ anode, strong degradation
                      occurs after redox cycling. In contrast, cells with a Ni/GDC
                      anode exhibit significantly improved redox tolerance and
                      cell performance improves with the number of redox cycles.
                      For understanding this behavior, microstructural
                      investigations of the Ni/GDC anode and the adjacent
                      electrolyte were performed by FIB-SEM. The long-term redox
                      behavior of MSCs with a Ni/GDC anode was also investigated
                      by conducting more comprehensive redox cycles at 400 °C,
                      500 °C, and 600 °C.},
      cin          = {IEK-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
                      (SOFC-20140602)},
      pid          = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000480664400015},
      doi          = {10.1016/j.jpowsour.2019.226751},
      url          = {https://juser.fz-juelich.de/record/864177},
}