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@ARTICLE{Chayambuka:864382,
author = {Chayambuka, K. and Mulder, G. and Danilov, Dmitri and
Notten, Peter H. L.},
title = {{A} modified pseudo-steady-state analytical expression for
battery modeling},
journal = {Solid state communications},
volume = {296},
issn = {0038-1098},
address = {New York, NY [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2019-04174},
pages = {49 - 53},
year = {2019},
abstract = {The solid-state spherical diffusion equation with flux
boundary conditions is a standard problem in lithium-ion
battery simulations. If finite difference schemes are
applied, many nodes across a discretized battery electrode
become necessary, in order to reach a good approximation of
solution. Such a grid-based approach can be appropriately
avoided by implementing analytical methods which reduce the
computational load. The pseudo-steady-state (PSS) method is
an exact analytical solution method, which provides accurate
solid-state concentrations at all current densities. The
popularization of the PSS method, in the existing form of
expression, is however constrained by a solution convergence
problem. In this short communication, a modified PSS (MPSS)
expression is presented which provides uniformly convergent
solutions at all times. To minimize computational runtime, a
fast MPPS (FMPPS) expression is further developed, which is
shown to be faster by approximately three orders of
magnitude and has a constant time complexity. Using the
FMPSS method, uniformly convergent exact solutions are
obtained for the solid-state diffusion problem in spherical
active particles.},
cin = {IEK-9},
ddc = {530},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000467930100010},
doi = {10.1016/j.ssc.2019.04.011},
url = {https://juser.fz-juelich.de/record/864382},
}