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@ARTICLE{Frank:864457,
      author       = {Frank, Michael and Jürgensen, Lasse and Leduc, Jennifer
                      and Stadler, Daniel and Graf, David and Gessner, Isabel and
                      Zajusch, Fabian and Fischer, Thomas and Rose, Marc-André
                      and Müller, David and Mathur, Sanjay},
      title        = {{V}olatile {R}henium({I}) {C}ompounds with {R}e–{N}
                      {B}onds and {T}heir {C}onversion into {O}riented {R}henium
                      {N}itride {F}ilms by {M}agnetic {F}ield-{A}ssisted {V}apor
                      {P}hase {D}eposition},
      journal      = {Inorganic chemistry},
      volume       = {58},
      number       = {15},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2019-04241},
      pages        = {10408 - 10416},
      year         = {2019},
      abstract     = {New heteroleptic rhenium(I) compounds, [fac-Re(I)(CO)3(L)]
                      (e.g., L= tfb-dmpda,
                      (N,N-(4,4,4-trifluorobut-1-en-3-on)-dimethyl propylene
                      diamine)), containing anionic and neutral ligands act as
                      efficient precursors to grow polycrystalline rhenium nitride
                      (ReN) films by their vapor phase deposition at 600 °C.
                      Deposition of ReN films under an external magnetic field
                      showed an orientation effect with preferred growth of
                      crystallites along ⟨100⟩ direction. Rhenium complexes
                      reported here unify high stability and reactivity in a
                      single molecule through a Janus-type coordination around a
                      Re center, constituted by a chelating tridentate ligand and
                      three carbonyl groups imparting a facial geometry.
                      Single-crystal diffraction analysis confirmed the structural
                      integrity of the new rhenium compounds. The rigidity of
                      molecular framework was validated in solution via 1D and 2D
                      NMR spectroscopy, in the gas phase via mass spectrometry,
                      and in the solid-state by thermogravimetric analysis and
                      differential scanning calorimetry studies. The analytical
                      data showed that pre-existent Re–N bonds in
                      [fac-Re(I)(CO)3(L)] facilitated low-temperature formation of
                      crystalline ReN deposits confirmed by grazing angle X-ray
                      diffraction analysis. The surface chemical composition and
                      the uniformity of microstructure were provided by X-ray
                      photoelectron spectroscopy (XPS) and scanning and
                      transmission electron microscopy (SEM/TEM), respectively.},
      cin          = {PGI-6 / PGI-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106 / I:(DE-Juel1)PGI-7-20110106},
      pnm          = {899 - ohne Topic (POF3-899) / DFG project 274005202 - SPP
                      1959: Manipulation of matter controlled by electric and
                      magnetic fields: Towards novel synthesis and processing
                      routes of inorganic materials (274005202)},
      pid          = {G:(DE-HGF)POF3-899 / G:(GEPRIS)274005202},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:31290653},
      UT           = {WOS:000480371400097},
      doi          = {10.1021/acs.inorgchem.9b01656},
      url          = {https://juser.fz-juelich.de/record/864457},
}