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@ARTICLE{Wang:864990,
      author       = {Wang, Liming and Kuchendorf, Christina and Willbold,
                      Sabine},
      title        = {{D}etermination of individual chain length and chain-length
                      distribution of polyphosphates in microalgae by
                      31{P}-{DOSY}-{NMR}},
      journal      = {Algal Research},
      volume       = {43},
      issn         = {2211-9264},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2019-04567},
      pages        = {101631 -101634},
      year         = {2019},
      abstract     = {Due to its ecological and biotechnological relevance,
                      polyphosphate in microalgae is currently the focus of
                      intense research. Numerous biological functions are
                      performed by or dependent on polyphosphate, and they depend,
                      among other factors, on its chain length. Chain length
                      determination is important for understanding polyphosphate
                      metabolism and for maximizing intracellular polyphosphate
                      abundance per unit weight of biomass. 31P-DOSY NMR virtually
                      separates various polyphosphate polymers in a mixture based
                      on different translational diffusion coefficients. The
                      diffusion coefficient of a polyphosphate molecule correlates
                      with its molecular weight, enabling determination of
                      individual chain lengths. Moreover, the polydispersity index
                      can also be uniquely determined by DOSY as a measure of the
                      overall chain-length distribution of polyphosphates. By
                      contrast, conventional 31P NMR is only able to estimate the
                      average chain length of the entire polyphosphate pool.
                      Therefore, DOSY provides the opportunity to deepen our
                      insight into polyphosphate metabolism and dynamics in algal
                      biomass.},
      cin          = {ZEA-3 / IBG-2},
      ddc          = {580},
      cid          = {I:(DE-Juel1)ZEA-3-20090406 / I:(DE-Juel1)IBG-2-20101118},
      pnm          = {582 - Plant Science (POF3-582)},
      pid          = {G:(DE-HGF)POF3-582},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000489307800010},
      doi          = {10.1016/j.algal.2019.101631},
      url          = {https://juser.fz-juelich.de/record/864990},
}