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| Hauptseite > Publikationsdatenbank > Silver Particles with Rhombicuboctahedral Shape and Effective Isotropic Interactions with Light > print |
| Hauptseite > Publikationsdatenbank > Silver Particles with Rhombicuboctahedral Shape and Effective Isotropic Interactions with Light > print |
| 001 | 865114 | ||
| 005 | 20240619092007.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.chemmater.8b05220 |2 doi |
| 024 | 7 | _ | |a 0897-4756 |2 ISSN |
| 024 | 7 | _ | |a 1520-5002 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2019-04666 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Steiner, Anja Maria |0 0000-0003-1881-2018 |b 0 |
| 245 | _ | _ | |a Silver Particles with Rhombicuboctahedral Shape and Effective Isotropic Interactions with Light |
| 260 | _ | _ | |a Washington, DC |c 2019 |b American Chemical Society |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Truly spherical silver nanoparticles are of great importance for fundamental studies including plasmonic applications, but their direct synthesis in aqueous media is not feasible. Using the commonly employed copper-based etching processes, an isotropic plasmonic response can be achieved by etching well-defined silver nanocubes. Whilst spherical-like shape is typically prevailing in such processes, we established that there is a preferential growth toward silver rhombicuboctahedra, which is the thermodynamically most stable product of this synthesis. The rhombicuboctahedral morphology is further evidenced by comprehensive characterization with small-angle X-ray scattering in combination with transmission electron microscopy (TEM) tomography and high-resolution TEM. We also elucidate the complete reaction mechanism based on UV–vis kinetic studies, and the postulated mechanism can also be extended to all copper-based etching processes |
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| 700 | 1 | _ | |a Mayer, Martin |0 0000-0003-4013-1892 |b 1 |
| 700 | 1 | _ | |a Schletz, Daniel |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Wolf, Daniel |0 0000-0001-5000-8578 |b 3 |
| 700 | 1 | _ | |a Formanek, Petr |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Hübner, René |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Dulle, Martin |0 P:(DE-Juel1)172746 |b 6 |
| 700 | 1 | _ | |a Förster, Stephan |0 P:(DE-Juel1)172658 |b 7 |
| 700 | 1 | _ | |a König, Tobias A. F. |0 0000-0002-8852-8752 |b 8 |
| 700 | 1 | _ | |a Fery, Andreas |0 0000-0001-6692-3762 |b 9 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acs.chemmater.8b05220 |g Vol. 31, no. 8, p. 2822 - 2827 |0 PERI:(DE-600)1500399-1 |n 8 |p 2822 - 2827 |t Chemistry of materials |v 31 |y 2019 |x 1520-5002 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/865114/files/acs.chemmater.8b05220.pdf |y Restricted |
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| 856 | 4 | _ | |y Published on 2019-03-18. Available in OpenAccess from 2020-03-18. |u https://juser.fz-juelich.de/record/865114/files/1910.07764.pdf |
| 856 | 4 | _ | |y Published on 2019-03-18. Available in OpenAccess from 2020-03-18. |x pdfa |u https://juser.fz-juelich.de/record/865114/files/1910.07764.pdf?subformat=pdfa |
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