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@INPROCEEDINGS{Vibhu:865873,
author = {Vibhu, Vaibhav and Vinke, Izaak C. and Eichel, Rüdiger-A.
and de Haart, L.G.J.},
title = {{C}obalt substituted {L}anthanide {N}ickelates
({L}n2-{N}i1-x{O}4+δ, {LN} = {L}a, {P}r; x = 0, 0.1, 0.2)
as {H}igh {P}erformance {O}xygen {E}lectrodes for {S}olid
{O}xide {C}ells},
volume = {91},
number = {1},
issn = {1938-5862},
address = {Pennington, NJ},
reportid = {FZJ-2019-05159},
isbn = {10.1149/09101.1327ecst},
pages = {1327-1339},
year = {2019},
abstract = {The present study is focused on the development of
alternative oxygen electrodes for Solid Oxide Fuel Cells
(SOFCs) and Solid Oxide Electrolyzers Cells (SOECs). Rare
earth nickelates with general formula Ln2NiO4+δ (Ln = La,
Pr or Nd) have shown good performance as oxygen electrodes
with various electrolytes. To further enhance the
physico-chemical properties, electrochemical performance as
oxygen electrode and durability of Solid Oxide Cells (SOCs),
herein, we have performed the substitution of nickel with
cobalt in these nickelates. Two compositions (x=0.1 and 0.2)
were mainly considered and completely characterized using
several techniques. The single cells were then prepared and
electrochemically characterized using DC- and AC-techniques
in the temperature range 700-900 °C. The durability test up
to 250h were also investigated at 1 A.cm-2 current density
at 800 °C under both SOFC (dry conditions) and SOEC
conditions (with $50\%$ H2 and $50\%$ H2O feed gas mixture)
indicating different degradation behavior.},
month = {Sep},
date = {2019-09-08},
organization = {16th International Symposium on Solide
Oxide Fuel Cells (SOFC-XVI), Kyoto
(Japan), 8 Sep 2019 - 13 Sep 2019},
cin = {IEK-9},
ddc = {540},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {135 - Fuel Cells (POF3-135)},
pid = {G:(DE-HGF)POF3-135},
typ = {PUB:(DE-HGF)8 / PUB:(DE-HGF)7},
doi = {10.1149/09101.1327ecst},
url = {https://juser.fz-juelich.de/record/865873},
}