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| Hauptseite > Publikationsdatenbank > Micromechanical Assessment of Al/Y-substituted NASICON Solid Electrolytes > print |
| Hauptseite > Publikationsdatenbank > Micromechanical Assessment of Al/Y-substituted NASICON Solid Electrolytes > print |
| 001 | 865916 | ||
| 005 | 20240709094327.0 | ||
| 024 | 7 | _ | |a 10.1016/j.ceramint.2019.07.114 |2 doi |
| 024 | 7 | _ | |a 0272-8842 |2 ISSN |
| 024 | 7 | _ | |a 0392-2960 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2019-05193 |
| 082 | _ | _ | |a 670 |
| 100 | 1 | _ | |a Nonemacher, Juliane Franciele |0 P:(DE-Juel1)168112 |b 0 |
| 245 | _ | _ | |a Micromechanical Assessment of Al/Y-substituted NASICON Solid Electrolytes |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2019 |b Elsevier Science |
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| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Al/Y-substituted NASICON solid electrolytes are promising for novel solid state batteries. The solid solutions Na1+2xAlxYxZr2-2x(PO4)3 (NAYZPx) and Na3+2xAlxYxZr2-2x(SiO4)2(PO4) (NAYZSiPx) that crystallize in this structure are characterized by depth-sensitive indentation technique to determine their micro-mechanical properties. NAYZPx is rhombohedral, whereas NAYZSiPx changes from monoclinic to rhombohedral phase depending on substitutional level and temperature. For rhombohedral NAYZPx elastic moduli are in the range ~72–82 GPa and hardness values are in the range ~4.8–5.8 GPa, whereas for NAYZSiPx the elastic moduli are with the range ~72–88 GPa and hardness ~5.6–7.6 GPa, respectively. The fracture toughness values for both systems, as determined by Vickers indentation, are rather independent of the applied load being with the range 1.30–1.58 MPa m0.5. Cracks typically show a mixed intergranular/transgranular crack mode. |
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| 700 | 1 | _ | |a Naqash, Sahir |0 P:(DE-Juel1)165865 |b 1 |u fzj |
| 700 | 1 | _ | |a Tietz, Frank |0 P:(DE-Juel1)129667 |b 2 |u fzj |
| 700 | 1 | _ | |a Malzbender, Jürgen |0 P:(DE-Juel1)129755 |b 3 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1016/j.ceramint.2019.07.114 |g Vol. 45, no. 17, p. 21308 - 21314 |0 PERI:(DE-600)2018052-4 |n 17A |p 21308 - 21314 |t Ceramics international |v 45 |y 2019 |x 0272-8842 |
| 856 | 4 | _ | |y Published on 2019-07-09. Available in OpenAccess from 2021-07-09. |u https://juser.fz-juelich.de/record/865916/files/11-jun-2019%20%20Micromechanical%20Assessment%20of%20AlY-substituted%20NASICON_vFT_vSN.pdf |
| 856 | 4 | _ | |y Published on 2019-07-09. Available in OpenAccess from 2021-07-09. |x pdfa |u https://juser.fz-juelich.de/record/865916/files/11-jun-2019%20%20Micromechanical%20Assessment%20of%20AlY-substituted%20NASICON_vFT_vSN.pdf?subformat=pdfa |
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