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@ARTICLE{EilersRethwisch:865961,
      author       = {Eilers-Rethwisch, M. and Hildebrand, S. and Evertz, M. and
                      Ibing, L. and Dagger, T. and Winter, M. and Schappacher, F.
                      M.},
      title        = {{C}omparative study of {S}n-doped
                      {L}i[{N}i0.6{M}n0.2{C}o0.2-{S}n ]{O}2 cathode active
                      materials (x = 0-0.5) for lithium ion batteries regarding
                      electrochemical performance and structural stability},
      journal      = {Journal of power sources},
      volume       = {397},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2019-05227},
      pages        = {68 - 78},
      year         = {2018},
      abstract     = {Layered Ni-rich Li[Ni0.6Mn0.2Co0.2-xSnx]O2 cathode active
                      materials with x = 0–0.05 are synthesized via a
                      co-precipitation synthesis route and the effect of doping
                      content on the structural behavior and electrochemical
                      performance are investigated. All synthesized materials show
                      a well-defined layered structure of the hexagonal α-NaFeO2
                      phase (space group Rm) analyzed by X-ray diffraction (XRD).
                      Electrochemical Li-metal/cathode cell studies exhibit that a
                      Sn-content of $1\%–2\%$ is beneficial regarding specific
                      discharge capacity and cycle life $(≥20\%).$ Detailed
                      electrochemical investigations of Li-metal and lithium ion
                      cells with cathodes consisting of LiNi0.6Mn0.2Co0.2O2 and
                      LiNi0.6Mn0.2Co0.18Sn0.02O2 are conducted. Post mortem
                      analyses by means of ICP-OES and TXRF show beneficial
                      effects of the Sn-doping with regard to a lower transition
                      metal dissolution and a higher available Li content in the
                      cathode active material. The thermal analyses (TGA, DSC,
                      ARC) show a stabilizing effect of Sn-doping, which results
                      from a lower mass loss and less heat evolution of the
                      charged cathode active materials at elevated temperatures.},
      cin          = {IEK-12},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000445317900010},
      doi          = {10.1016/j.jpowsour.2018.06.072},
      url          = {https://juser.fz-juelich.de/record/865961},
}