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| 100 | 1 | _ | |a Eilers-Rethwisch, M. |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Comparative study of Sn-doped Li[Ni0.6Mn0.2Co0.2-Sn ]O2 cathode active materials (x = 0-0.5) for lithium ion batteries regarding electrochemical performance and structural stability |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2018 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Layered Ni-rich Li[Ni0.6Mn0.2Co0.2-xSnx]O2 cathode active materials with x = 0–0.05 are synthesized via a co-precipitation synthesis route and the effect of doping content on the structural behavior and electrochemical performance are investigated. All synthesized materials show a well-defined layered structure of the hexagonal α-NaFeO2 phase (space group Rm) analyzed by X-ray diffraction (XRD). Electrochemical Li-metal/cathode cell studies exhibit that a Sn-content of 1%–2% is beneficial regarding specific discharge capacity and cycle life (≥20%). Detailed electrochemical investigations of Li-metal and lithium ion cells with cathodes consisting of LiNi0.6Mn0.2Co0.2O2 and LiNi0.6Mn0.2Co0.18Sn0.02O2 are conducted. Post mortem analyses by means of ICP-OES and TXRF show beneficial effects of the Sn-doping with regard to a lower transition metal dissolution and a higher available Li content in the cathode active material. The thermal analyses (TGA, DSC, ARC) show a stabilizing effect of Sn-doping, which results from a lower mass loss and less heat evolution of the charged cathode active materials at elevated temperatures. |
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| 700 | 1 | _ | |a Ibing, L. |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Dagger, T. |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Winter, M. |0 P:(DE-Juel1)166130 |b 5 |e Corresponding author |u fzj |
| 700 | 1 | _ | |a Schappacher, F. M. |0 0000-0002-3743-8837 |b 6 |e Corresponding author |
| 773 | _ | _ | |a 10.1016/j.jpowsour.2018.06.072 |g Vol. 397, p. 68 - 78 |0 PERI:(DE-600)1491915-1 |p 68 - 78 |t Journal of power sources |v 397 |y 2018 |x 0378-7753 |
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