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| Home > Publications database > Synthesis, electrochemical investigation and structural analysis of doped Li[Ni0.6Mn0.2Co0.2-M]O2 (x = 0, 0.05; M = Al, Fe, Sn) cathode materials > print |
| Home > Publications database > Synthesis, electrochemical investigation and structural analysis of doped Li[Ni0.6Mn0.2Co0.2-M]O2 (x = 0, 0.05; M = Al, Fe, Sn) cathode materials > print |
| 001 | 865963 | ||
| 005 | 20240712113123.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jpowsour.2018.02.080 |2 doi |
| 024 | 7 | _ | |a 0378-7753 |2 ISSN |
| 024 | 7 | _ | |a 1873-2755 |2 ISSN |
| 024 | 7 | _ | |a WOS:000430899800013 |2 WOS |
| 037 | _ | _ | |a FZJ-2019-05229 |
| 082 | _ | _ | |a 620 |
| 100 | 1 | _ | |a Eilers-Rethwisch, Matthias |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Synthesis, electrochemical investigation and structural analysis of doped Li[Ni0.6Mn0.2Co0.2-M]O2 (x = 0, 0.05; M = Al, Fe, Sn) cathode materials |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2018 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1571920044_10926 |2 PUB:(DE-HGF) |
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| 520 | _ | _ | |a Layered Ni-rich Li[Ni0.6Mn0.2Co0.2-xMx]O2 cathode materials (x = 0, 0.05; M = Al, Fe, Sn) are synthesized via a co-precipitation synthesis route and the effect of dopants on the structure and electrochemical performance is investigated. All synthesized materials show a well-defined layered structure of the hexagonal α-NaFeO2 phase investigated by X-ray diffraction (XRD). Undoped LiNi0.6Mn0.2Co0.2O2 exhibits a discharge capacity of 170 mAh g−1 in Li-metal 2032 coin-type cells. Doped materials reach lower capacities between 145 mAh g−1 for Al and 160 mAh g−1 for Sn. However, all doped materials prolong the cycle life by up to 20%. Changes of the lattice parameter before and after delithiation yield information about structural stability. A smaller repulsion of the transition metal layer during delithiation in the Sn-doped material leads to a smaller expansion of the unit cell, which results in enhanced structural stability of the material. The improved structural stability of Sn-doped NMC cathode active material is proven by thermal investigations with the help of Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). |
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| 700 | 1 | _ | |a Winter, Martin |0 P:(DE-Juel1)166130 |b 1 |e Corresponding author |u fzj |
| 700 | 1 | _ | |a Schappacher, Falko Mark |0 0000-0002-3743-8837 |b 2 |e Corresponding author |
| 773 | _ | _ | |a 10.1016/j.jpowsour.2018.02.080 |g Vol. 387, p. 101 - 107 |0 PERI:(DE-600)1491915-1 |p 101 - 107 |t Journal of power sources |v 387 |y 2018 |x 0378-7753 |
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