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@ARTICLE{Beltrop:865964,
author = {Beltrop, Kolja and Qi, Xin and Hering, Tobias and Röser,
Stephan and Winter, Martin and Placke, Tobias},
title = {{E}nabling bis(fluorosulfonyl)imide-based ionic liquid
electrolytes for application in dual-ion batteries},
journal = {Journal of power sources},
volume = {373},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2019-05230},
pages = {193 - 202},
year = {2018},
abstract = {In this work, we present a comprehensive study on the
effect of adding different conductive salt additives
including LiPF6, LiBF4 and LiDFOB, as well as the
fluorinated solvent additive methyl difluoroacetate (MDFA)
to a bis(fluorosulfonyl)imide (FSI)-based ionic liquid (IL)
electrolyte, i.e. Pyr14FSI/LiFSI, to protect the Al current
collector (ACC) from anodic dissolution and, thus, enable
reversible charge/discharge cycling in a high performance
dual-ion cell. Chronocoulometry and scanning electron
microscopy measurements were conducted to evaluate the
specific ACC passivation ability of each electrolyte.
Furthermore, the influence of these additives on anion
intercalation behavior into the graphite positive electrode
with special emphasis on the Coulombic efficiency (CE),
reversible capacity, as well as capacity retention is
presented. Overall, we can show that the addition of small
amounts of LiPF6, LiBF4 and MDFA (0.5 $wt\%)$ into the
FSI-based IL electrolyte significantly increases the overall
cell performance, whereas LiDFOB as electrolyte additive
deteriorates the dual-ion cell performance. In addition, an
excellent cycling performance for 1000 cycles is obtained
for the Pyr14FSI electrolyte having 5 $wt\%$ LiPF6,
displaying an average reversible capacity of 40 mAh g−1, a
CE exceeding $98\%$ and a capacity retention of $91\%,$
which has not been reported so far.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000418392000021},
doi = {10.1016/j.jpowsour.2017.11.010},
url = {https://juser.fz-juelich.de/record/865964},
}