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@ARTICLE{Larsson:866047,
      author       = {Larsson, Johan and Sanchez-Fernandez, Adrian and Mahmoudi,
                      Najet and Barnsley, Lester C. and Wahlgren, Marie and
                      Nylander, Tommy and Ulvenlund, Stefan},
      title        = {{E}ffect of the {A}nomeric {C}onfiguration on the
                      {M}icellization of {H}exadecylmaltoside {S}urfactants},
      journal      = {Langmuir},
      volume       = {35},
      number       = {43},
      issn         = {1520-5827},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {FZJ-2019-05293},
      pages        = {13904 - 13914},
      year         = {2019},
      abstract     = {The self-assembly of the two anomeric forms of
                      n-hexadecyl-d-maltopyranoside (denoted α-C16G2 and
                      β-C16G2) has been studied in dilute aqueous solution by
                      means of surface tension measurements, scattering methods
                      (dynamic light scattering, static light scattering, and
                      small-angle X-ray and neutron scattering), and
                      cryo-transmission electron microscopy at different
                      surfactant concentrations and temperatures. Surface tension
                      measurements demonstrate differences in the surfactant
                      adsorption at the air–water interface, where α-C16G2
                      shows a lower CMC than β-C16G2. Similarly, micelle
                      morphology was found to profoundly depend on anomerism.
                      β-C16G2 preferentially forms very elongated micelles with
                      large persistence lengths, whereas α-C16G2 assembles into
                      smaller micelles for which the structure varies with
                      concentration and temperature. The differences between the
                      two surfactant anomers in terms of self-assembly can be
                      attributed to the interaction between neighboring
                      headgroups. Specifically, β-C16G2 allows for a closer
                      packing in the palisade layer, hence reducing the micelle
                      curvature and promoting the formation of more elongated
                      micelles. Strong intermolecular headgroup interactions may
                      also account for the observed rigidity of the micelles.},
      cin          = {JCNS-FRM-II / JCNS-1 / MLZ},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-588b)4597118-3},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6G15 - FRM II / MLZ (POF3-6G15)},
      pid          = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:31566987},
      UT           = {WOS:000493586900012},
      doi          = {10.1021/acs.langmuir.9b01960},
      url          = {https://juser.fz-juelich.de/record/866047},
}