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@ARTICLE{Rothenbach:866227,
author = {Rothenbach, N. and Gruner, M. E. and Ollefs, K. and
Schmitz-Antoniak, C. and Salamon, S. and Zhou, P. and Li, R.
and Mo, M. and Park, S. and Shen, X. and Weathersby, S. and
Yang, J. and Wang, X. J. and Pentcheva, R. and Wende, H. and
Bovensiepen, U. and Sokolowski-Tinten, K. and Eschenlohr,
A.},
title = {{M}icroscopic nonequilibrium energy transfer dynamics in a
photoexcited metal/insulator heterostructure},
journal = {Physical review / B},
volume = {100},
number = {17},
issn = {0163-1829},
address = {Woodbury, NY},
publisher = {Inst.},
reportid = {FZJ-2019-05393},
pages = {174301},
year = {2019},
abstract = {The element specificity of soft x-ray spectroscopy makes it
an ideal tool for analyzing the microscopic origin of
ultrafast dynamics induced by localized optical excitation
in metal-insulator heterostructures. Using [Fe/MgO]n as a
model system, we perform ultraviolet pump/soft x-ray probe
experiments, which are sensitive to all constituents of
these heterostructures, to probe both electronic and lattice
excitations. Complementary ultrafast electron diffraction
experiments independently analyze the lattice dynamics of
the Fe constituent, and together with ab initio calculations
yield comprehensive insight into the microscopic processes
leading to local relaxation within a single constituent or
nonlocal relaxation between two constituents. Besides
electronic excitations in Fe, which are monitored at the Fe
L3 absorption edge and relax within 1 ps by electron-phonon
coupling, soft x-ray analysis identifies a change at the
oxygen K absorption edge of the MgO layers which occurs
within 0.5 ps. This ultrafast energy transfer across the
Fe-MgO interface is mediated by high-frequency, interface
vibrational modes, which are excited by hot electrons in Fe
and couple to vibrations in MgO in a mode-selective,
nonthermal manner. A second, slower timescale is identified
at the oxygen K pre-edge and the Fe L3 edge. The slower
process represents energy transfer by acoustic phonons and
contributes to thermalization of the entire heterostructure.
We thus find that the interfacial energy transfer is
associated with nonequilibrium behavior in the phonon
system. Because our experiments lack signatures of charge
transfer across the interface, we conclude that
phonon-mediated processes dominate the competition of
electronic and lattice excitations in these nonlocal,
nonequilibrium dynamics.},
cin = {PGI-6},
ddc = {530},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000494449700001},
doi = {10.1103/PhysRevB.100.174301},
url = {https://juser.fz-juelich.de/record/866227},
}