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@ARTICLE{Motalov:866469,
      author       = {Motalov, V. and Bencze, L. and Yin, X. and Spatschek, R.
                      and Singheiser, L.},
      title        = {{M}easurment of {T}hermodynamic {A}ctivity of {Z}irconia in
                      {Y}ttria-{S}tabilized {Z}irconia {E}lectrolyte for {S}olid
                      {O}xide {F}uel {C}ell {A}pplication},
      journal      = {Calphad},
      volume       = {64},
      issn         = {0364-5916},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2019-05580},
      pages        = {342 - 346},
      year         = {2019},
      abstract     = {The Knudsen effusion mass spectrometry technique was
                      applied to determine the activity of ZrO2 in $8 mol\%$
                      yttria-stabilized zirconia (8YSZ) in the temperature range
                      from 2200 K to 2500 K. The minor ZrO2+ ion current was
                      used in calculations instead of the prevailing ZrO+ signal.
                      The phase stability of the samples and their negligible
                      interaction with the cell material was proved by
                      XRD-analysis. The activity of ZrO2 was obtained to be
                      0.84 ± 0.04 independent of temperature. This fact
                      allows estimating the same value of activity in the
                      operating temperature range of solid oxide fuel cells
                      (SOFCs).},
      cin          = {IEK-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-2-20101013},
      pnm          = {113 - Methods and Concepts for Material Development
                      (POF3-113)},
      pid          = {G:(DE-HGF)POF3-113},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000460842600037},
      doi          = {10.1016/j.calphad.2019.01.010},
      url          = {https://juser.fz-juelich.de/record/866469},
}