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100 1 _ |a Motalov, V.
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245 _ _ |a Measurment of Thermodynamic Activity of Zirconia in Yttria-Stabilized Zirconia Electrolyte for Solid Oxide Fuel Cell Application
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a The Knudsen effusion mass spectrometry technique was applied to determine the activity of ZrO2 in 8 mol% yttria-stabilized zirconia (8YSZ) in the temperature range from 2200 K to 2500 K. The minor ZrO2+ ion current was used in calculations instead of the prevailing ZrO+ signal. The phase stability of the samples and their negligible interaction with the cell material was proved by XRD-analysis. The activity of ZrO2 was obtained to be 0.84 ± 0.04 independent of temperature. This fact allows estimating the same value of activity in the operating temperature range of solid oxide fuel cells (SOFCs).
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700 1 _ |a Bencze, L.
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700 1 _ |a Yin, X.
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700 1 _ |a Spatschek, R.
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700 1 _ |a Singheiser, L.
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