TY  - JOUR
AU  - Yang, Xiaosheng
AU  - Egger, Larissa
AU  - Fuchsberger, Jana
AU  - Unzog, Martin
AU  - Lüftner, Daniel
AU  - Hajek, Felix
AU  - Hurdax, Philipp
AU  - Jugovac, Matteo
AU  - Zamborlini, Giovanni
AU  - Feyer, Vitaliy
AU  - Koller, Georg
AU  - Puschnig, Peter
AU  - Tautz, F. Stefan
AU  - Ramsey, Michael G.
AU  - Soubatch, Serguei
TI  - Coexisting Charge States in a Unary Organic Monolayer Film on a Metal
JO  - The journal of physical chemistry letters
VL  - 10
IS  - 21
SN  - 1948-7185
CY  - Washington, DC
PB  - ACS
M1  - FZJ-2019-05585
SP  - 6438 - 6445
PY  - 2019
AB  - The electronic and geometric structures of tetracene films on Ag(110) and Cu(110) have been studied with photoemission tomography and compared to that of pentacene. Despite similar energy level alignment of the two oligoacenes on these surfaces revealed by conventional ultraviolet photoelectron spectroscopy, the momentum-space resolved photoemission tomography reveals a significant difference in both structural and electronic properties of tetracene and pentacene films. Particularly, the saturated monolayer of tetracene on Ag(110) is found to consist of two molecular species that, despite having the same orientation, are electronically very different—while one molecule remains neutral, another is charged because of electron donation from the substrate.
LB  - PUB:(DE-HGF)16
C6  - pmid:31573816
UR  - <Go to ISI:>//WOS:000495805100002
DO  - DOI:10.1021/acs.jpclett.9b02231
UR  - https://juser.fz-juelich.de/record/866483
ER  -