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@PHDTHESIS{Schleicher:866546,
author = {Schleicher, Sebastian},
title = {{C}hemisorption aromatischer {M}oleküle auf
Übergangsmetalloberflächen: {B}ildung molekularer
{H}ybridmagnete},
volume = {208},
school = {Universität Köln},
type = {Dr.},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2019-05636},
isbn = {978-3-95806-442-3},
series = {Schriften des Forschungszentrums Jülich. Reihe
Schlüsseltechnologien / Key Technologies},
pages = {107 S.},
year = {2019},
note = {Universität Köln, Diss., 2019},
abstract = {The goal of molecular spintronics is to use molecules for
the realization of smallest switchable magnetic units. The
molecules serve as building blocks of future electronic
devices to increase their integration density and energy
effciency. The interaction of individual molecules and
molecular monolayers with metal surfaces is one of the key
properties and needs to be investigated and controlled. To
this end, well-defined and controlled adsorption of
molecules with sub-monolayer coverage onto clean
single-crystalline surfaces of (transition) metals under
ultra-high vacuum conditions is required. In this PhD
thesis, the chemisorption of three aromatic molecules on
different transition metal surfaces and the associated
formation of molecular hybrid magnets was investigated. This
research was inspired by the experimental evidence of a
molecule-based spin filter effect in mesoscopic junctions
given by Raman et al. This thesis focuses on the basics with
regard to the experimental realization of the spin-filter
effect in a single double-decker molecule. The theoretically
proposed spin-filter mechanism is based on the adsorption of
intrinsically non-magnetic flat aromatic molecules on
ferromagnetic surfaces, whereby strong hybridization of
molecular 𝜋-orbitals with spin-split 𝑑-orbitals of the
substrate occurs. The resulting imbalance of spin-resolved
states of the adsorbed molecule induces magnetic properties
in the molecule such as a spin-dependent band gap, a stable
magnetic moment, or spin polarization at the Fermi energy.
The induced magnetic properties as well as the atomic and
electronic structure of the molecule-substrate hybrid
systems are investigated by (spin-polarized) scanning
tunneling microscopy and spectroscopy in ultra-high vacuum
and at low temperatures (4 K). [...]},
cin = {PGI-6},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {522 - Controlling Spin-Based Phenomena (POF3-522)},
pid = {G:(DE-HGF)POF3-522},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/866546},
}